Research

Anisotropic colloids at fluid-fluid interfaces

Principal investigator:

The irreversible entrapment of anisotropic colloidal particles at fluid-fluid interfaces can be exploited to make permeable capsules, to stabilize foams and emulsions, and to make two-dimensional functional materials by assembling colloidal building blocks. In collaboration with Prof. Stebe (Dept. of Chem. Eng, University of Pennsylvania), I study the mechanical properties of these capillary systems. Ours is a concerted effort that relies on simulation, theory and experiments.

Fig. 1 A micro-cylinder embedded at the interface between two immiscible fluids. Because of the need to satisfy the contact angle at a complex-shape boundary, the cylinders induces a distortion of the interface.Fig. 2 Overlapping of interface distortions by neighbouring particles induces oriented capillary self-assembly, as seen from this experimental picture with lithographically-defined cylindrical colloids.