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Queen Mary University of LondonQueen Mary University of London
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School of Engineering and Materials Science
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PhD Thesis: Large section ceramic injection moulding

Author: KRUG, Steffen

Year: 2000

Supervisor(s): Julian Evans

Ceramic injection moulding is already established as a production technique for complex shaped ceramic components. However the process is limited to thin section mouldings generally not exceeding a wall thickness of 10 mm. The global objective of this work is to describe and understand the aetiology of defects which preferentially appear in thick injection moulded ceramics, and to find ways to overcome these problems.
The following stages are examined - mould-filling, solidification, binder removal and sintering. Different moulding techniques; conventional moulding, modulated pressure moulding, insulated sprue moulding and low hold pressure moulding were applied. Moulding thickness was systematically varied (15, 20, 25,and 35 mm). Hold pressures and times were closely controlled and found to be decisive processing parameters for defect creation. The use of insulated spruce moulding prevented void formation in 25 mm thick mouldings and the application of low and constant hold pressures (>5 MPa) led to a reduction of residual stresses in the mouldings.

An intensive study was carried out on the binder removal state in which the catalytic removal of the polyacetal binder enabled removal of the binder from sections of 35 mm thickness. The reaction and transport kinetics during binder removal were studied and close observations were carried out on various defects which could appear during interrupted binder removal.

Differential shrinkage of the ceramic components during sintering was studied and could be tracked back to flow-induced particle alignment during mould filling. The sintering behaviour of the alumina feedstock used in this study was compared with an equiaxed zirconia powder injection moulding suspension. The phenomenon of jetting in large section mouldings and the creation of spherulites during solidification of the polymer were found to influence moulding structure.