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Queen Mary University of LondonQueen Mary University of London
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School of Engineering and Materials Science
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PhD Thesis: Processing and sintering of carbonate hydroxyapatite

Author: BARRALET, Jake

Year: 1995

Supervisor(s): Bill Bonfield

Since the early 1970's there have been a number of investigations into the preparation of dense sintered hydroxyapatite for medical applications. However, there have been few studies reporting the production of sintered carbonate apatite, which resembles more closely the composition of human bone mineral.
This work has studied the precipitation, processing and sintering of carbonate apatites. Crystallisation variables such as temperature and bicarbonate ion concentration have been investigated in order to determine some effects on the size, morphology and composition of carbonate apatite precipitates. By employing the correct conditions, nanoscale precipitates have been produced that have enabled the use of a colloidal filtration route in processing. The effect of sintering atmosphere, green density, and carbonate content were investigated isochronally over a range of temperatures. Isothermal experiments demonstrated the evolution of microstructure and changes in density with time.

Results from this study indicated that translucent 99.9% relative density carbonate hydroxyapatite could be produced by sintering in an atmosphere of carbon dioxide and water. Water was found to enhance densification in carbon dioxide furnace atmospheres. The temperature at which maximum densification occurred decreased with carbonate content. Bloating was found to be related to carbonate content as larger expansions were observed in higher carbonate content materials. The partial pressure of water did not effect the composition of the carbonate apatite, whereas the green composition did, contrary to the findings of other workers.