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Direct magnetoelectric coupling from magnetically/ferroelectrically active cation in low symmetric octahedron

27 August 2025

Schematic for multiferroicity of distorted FeO6 octahedrons.  The ferromagnetic superexchange interaction between Fe3+-O-Fe2+ with an angle θ leads to the coexistence of ferromagnetism and ferroelectricity. Manipulating the angle θ offers possibilities for controlling the magnetoelectric properties of distorted FeO6 octahedrons
Schematic for multiferroicity of distorted FeO6 octahedrons. The ferromagnetic superexchange interaction between Fe3+-O-Fe2+ with an angle θ leads to the coexistence of ferromagnetism and ferroelectricity. Manipulating the angle θ offers possibilities for controlling the magnetoelectric properties of distorted FeO6 octahedrons
Intrinsic magnetoelectric coupling characterized by the resonant behaviour of the complex dielectric permittivity and complex magnetic permeability at microwave frequencies
Intrinsic magnetoelectric coupling characterized by the resonant behaviour of the complex dielectric permittivity and complex magnetic permeability at microwave frequencies

The ability of magnetoelectric (ME) multiferroics to couple magnetic and ferroelectric orders suggests that they have the potential to add functionality to devices while also reducing energy consumption. Yet, achieving strong and direct ME coupling in single-phase multiferroic at room temperature remains highly challenging.

Here, we demonstrate that lowering the symmetry of BiFeO3 through oxygen octahedron distortion and controlled tilting is possible to develop room temperature multiferroics in which ferroelectricity and ferromagnetism share a common origin. The resulting multiferroic shows room temperature dynamic ME effect, as evidenced by the resonant features of the complex dielectric permittivity and complex magnetic permeability at microwave frequencies.

This new room-temperature multiferroic material provides great potential for construction of low-energy non-volatile magnetoelectric storages and sensors. [Phys. Rev. B 112, 054423 – Published 8 August, 2025]

Contact:Zixuan Wu and Haixue Yan
Website:https://journals.aps.org/prb/abstract/10.1103/h4kv-qszp
People:Haixue YAN